Physical Review Letters 75(2), 296 (1995).
We analyze optical absorption, transmission, luminescence, and Raman scattering in n-type GaN at hydrostatic pressures up to 30 GPa. The results show freeze-out of free electrons above ~= (approximately-equal-to) 20GPa due to trapping at levels that are resonant at ambient pressure but become gap states at high pressures. Ab initio calculations show that both the N vacancy and the Ga interstitial undergo this transition at ~= (approximately-equal-to) 20 GPa, but the vacancy should be more abundant. The pressure dependence of the yellow luminescence indicates that a transition between a shallow donor and a deep acceptor is involved.
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