Physical Review B 53(24), 16425 (1996).
The optical absorption near the fundamental absorption edge in GaN thin films grown on sapphire substrates using the metalorganic chemical-vapor deposition technique is studied as a functionof temperature. The absorption spectrum shows a free-exciton peak at 353.55 nm and a shoulder at 354.67 nm, which is attributed to a bound exciton. The absorption band edge was determined fromthe energy position of the exciton line observed in the entire temperature range of 13- 300 K. The band-edge energies determined in this temperature range were fitted with the Varshniempirical relationship Eg(K)=E[sub g](0)-sigmaT2/(T+thetaD) and with the expression Eg(K)=Eg(0)-kappa/[exp(theta[sub E]/T)-1]. The results show that thetaD~= (approximately-equal-to) 737.9 K in agreement with thecalculated value. © 1996 The American Physical Society.[S0163-1829(96)03424-8]
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