Physical Review B 50(12), 8433 (1994).
The temperature-dependent (10-300 K) optical band gap E0(T) of the epitaxial metastable zinc-blende-structure beta - GaN(001)4 (times) 1 has been determined by modulated photoreflectance and used to interpret low-temperature photoluminescence spectra. E0 in beta -GaN was found to vary from 3.302+- (plus-minus) 0.004 eV at 10 K to 3.231+- (plus-minus) 0.008 eV at 300 K with a temperature dependence given by E0(T) =3.302-6.697 (times) 10-4T2/(T+600) eV. The spin-orbit splitting Delta 0 in the valence band was determined to be 17+- (plus-minus) 1 meV. The oscillations in the photoreflectance spectra were very sharp with a broadening parameter Gamma of only 10 meV at 10 K. The dominant transition observed in temperature-dependent photoluminescence was attributed to radiative recombination between a shallow donor, at ~= (congruent) 11 meV below the conduction-band edge and the valence band.
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