Journal of Applied Physics 76(2), 1210 (1994).
Ion milling of thin-film GaN, InN, AIN, and InGaN was performed with 100-500 eV Ar(+) ions at beam angles of incidence ranging from 0 deg to 75 deg from normal incidence. The mill rates normalized to the Ar(+) beam current for the single-crystal GaN, AIN, and InGaN were typically a factor of 2 lower than for GaAs and InP. For the polycrystalline InM, the mill rates were similar to those of GaAs and InP. The surface morphology of the ion-milled nitrides was smooth even at 500 eV Ar(+) energy with no evidence for preferential sputtering of the N, a result confirmed by Auger electron spectroscopy. The surface region was not amorphized by extended ion milling (35 min) at 500 eV with the samples held at 10 C, as determined by Rutherford backscattering. Since the ion mill rates are slow for single-crystal nitrides and less than the mill rates of common masking materials (SiO2 SiN(sub x) photoresist) it appears this technique is useful only for shallow -mesa applications, and that dry etching methods involving an additonal chemical component or ion implantation isolation are more practical alternatives for device patterning.
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Contributed by the Journalmaster. More information is available from NASA's ADS database, with bibcode 1994JAP....76.1210P
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