Phonons and Free Carriers in a Strained Hexagonal GaN-AlN Superlattice Measured by Infrared Ellipsometry and Raman Spectroscopy


Mathias M Schubert
University Nebraska

Alexander Kasic
University Leipzig

Tomas E Tiwald, John A Woollam
University Nebraska

Volker Haerle
Osram Opto Semiconductors

Ferdinand Scholz
Univ. Stuttgart

This article was presented as part of Symposium W, "Gallium Nitride and Related Alloys" at the 1999 Fall Meeting of the Materials Research Society held in Boston, Massachusetts, November 28-December 3

Abstract

Phonon and free-carrier effects in a strained hexagonal ( alpha ) {GaN}l-{AlN}m superlattice (SL) heterostructure (l = 8 nm, m = 3 nm) are studied by infrared spectroscopic ellipsometry (IRSE) and micro (µ)-Raman scattering. Growth of the heterostructures was performed by metal-organic vapor phase epitaxy (MOVPE) on (0001) sapphire. An unstrained 1 µm-thick alpha-GaN layer was deposited prior to the SL. SL phonon modes are identified combining results from both IRSE and µ-Raman techniques. The shift of the GaN-sublayer phonon modes is used to estimate an average compressive SL stress of sigmaxx ~ - 4.3 GPa. The IRSE data reveal a free-carrier concentration of ne ~ 5x1018 cm-3 within the undoped SL GaN-sublayers. According to the vertical carrier confinement, the free-carrier mobility is anisotropic, and the lateral mobility ( µ~ 400 cm2/Vs, polarization E c-axis) exceeds the vertical mobility ( µ|| ~ 24 cm2/Vs, E||c) by one order of magnitude.

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Cite this article as: MRS Internet J. Nitride Semicond. Res. 5S1, W11.39 (2000).


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MRS Internet Journal of Nitride Semiconductor Research
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