Tables

Table I

Boiling points for possible etch products of Group-III nitride films etched in halogen- or CH4/H2-based plasmas.
Etch Products Boiling Points (°C)
AlCl3 183
AlF3 na
AlI3 360
AlBr3 263
(CH3)3Al 126
GaCl3 201
GaF3 1000
GaI3 sublimes 345
GaBr3 279
(CH3)3Ga 55.7
InCl3 600
InF3 >1200
InI3 na
InBr3 sublimes
(CH3)3In 134
NCl3 <71
NF3 -129
NBr3 na
NI3 explodes
NH3 -33
N2 -196
(CH3)3N -33

Table II

Summary of etch rate results for GaN, AlN and InN with different plasma chemistries in different techniques.
Gas Chemistry Etching Technique Etch rate (nm/min) at given bias



GaN ref
AlN ref
InN ref
SiCl4 [w/Ar, SiF4] RIE 55 -400 V [6] - -
- -
BCl3 RIE 105 -230 V [6] - -
- -
HBr [w/Ar, H2] RIE 60 -400 V [6] - -
- -
CHF3, C2ClF5 RIE 45 500 W [5] - -
- -
SF6 RIE 17 -400 V [6] - -
- -
CHF3, C2ClF5 RIE 60 -500 V [6] - -
- -
BCl3/Ar ECR 30 -250 V [5] 17 -250 V [5] 17 -300 V [5]
CCl2F2/Ar ECR 20 -250 V [5] 18 -300 V [5] 18 -300 V [5]
CH4/H2/Ar ECR 40 -250 V [5] 2.5 -300 V [5] 10 -300 V [5]
Cl2/H2/Ar ECR 200 -180 V [8] 110 -150 V [8] 150 -180 V [8]
SiCl4/Ar ECR 95 -280 V [8] - -
- -
Hl/H2 ECR 110 -150 V [5] 120 -150 V [5] 100 -150 V [7]
HBr/H2 ECR 70 -150 V [5] 65 -150 V [5] 17 -150 V [5]
ICl/Ar ECR 1300 -275 V [5] 200 -272 V [5] 1150 -275 V [5]
IBr/Ar ECR 300 -170 V [12] 160 -170 V [5] 325 -170 V [12]
BCl3 M-RIE 350 <-100 V [10] 125 <-100 V [5] 100 <-100 V [10]
Cl2/H2/Ar ICP 688 -280 V [8] - -
- -
Cl2/Ar ICP 980 -450 V [8] 670 -450 V [8] 150 -100 V [8]
Cl2/N2 ICP 65 -100 V [8] 39 -100 V [8] 30 -100 V [8]
BBr3 ICP 150 -380 [5] 50 -200 [5] 500 -380 [5]
BI3 ICP 200 -175 [5] 100 -175 [5] 700 -240 [5]
Icl ICP 30 -300 [5] 30 -300 [5] 600 -300 [5]
Ibr ICP 20 -300 [5] 30 -300 [5] 600 -300 [5]
Ar ion Ion milling 110 500 eV [5] 29 500 eV [5] 61 500 eV [5]
Cl2 [Ar ion] CAIBE 210 500 eV [6] 62 500 eV [6] - -
HCl[Ar ion] CAIBE 190 500 eV [6] - -
- -
Cl2 RIBE 150 500 eV [5] - -
- -
HCl RIBE 130 500 eV [5] - -
- -
Cl2/Ar RIBE 50 -400 [5] 50 -400 [5] 80 -400 [5]
HCl Photoassisted 0.04Å/pulse [6] - -
- -
H2, Cl2 LE4 50-70 1-15 eV [9] - -
- -

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last updated Wednesday, November 22, 2000 3:02:50 PM.

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