The Behavior of Ion-Implanted Hydrogen in Gallium Nitride


S.M. Myers, T.J. Headley, C.R. Hills, J. Han, G.A. Petersen, C.H. Seager, W.R. Wampler
Sandia National Laboratories

This article was presented as part of Symposium G, "Gallium Nitride and Related Alloys" at the 1998 Fall Meeting of the Materials Research Society held in Boston, Massachusetts, November 30-December 4.

Abstract

Hydrogen was ion-implanted into wurtzite-phase GaN, and its transport, bound states, and microstructural effects during annealing up to 980°C were investigated by nuclear-reaction profiling, ion-channeling analysis, transmission electron microscopy, and infrared (IR) vibrational spectroscopy. At implanted concentrations gap1 at.%, faceted H2 bubbles formed, enabling identification of energetically preferred surfaces, examination of passivating N-H states on these surfaces, and determination of the diffusivity-solubility product of the H. Additionally, the formation and evolution of point and extended defects arising from implantation and bubble formation were characterized. At implanted H concentrations lap0.1 at.%, bubble formation was not observed, and ion-channeling analysis indicated a defect-related H site located within the [0001] channel.

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Cite this article as: MRS Internet J. Nitride Semicond. Res. 4S1, G5.8 (1999).


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MRS Internet Journal of Nitride Semiconductor Research
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