S. Haffouz, B. Beaumont, Pierre GIBART
Centre de Recherche sur l'Hétéroépitaxie et ses Applications, CRHEA-CNRS
Metalorganic
vapor phase epitaxy was used to achieve selective regrowth of undoped, Mg- and
Si-doped GaN on a silicon nitride patterned mask, capping a GaN epitaxial layer
deposited on (0001) sapphire substrate. Hexagonal openings in the mask defined
into 10 µm diameter circles separated by 5µm were used as a pattern
for the present study. Uniform undoped and Mg-doped GaN hexagonal pyramids,
delimited by C (0001) and R {101} facets, were achieved with a good
selectivity. Si-doped GaN hexagonal pyramids delimited by vertical {1
00}
facets and (0001) top facet were obtained for a high SiH4 flow rate
in the vapor phase. We found that the GaN growth rates VR and
VC, measured in the R <1
01> and C <0001>
directions respectively, were drastically affected by the Mg and Si
incorporation. By adjusting the Mg partial pressure in the growth chamber, the
VR/VC ratio can be increased. Hence, the delimiting top
C facet do not vanish as usually observed in undoped GaN selective regrowth but
conversely expands. On the other hand, under proper growth conditions,
20µm-high Si-doped GaN columns were obtained.