Effect of Magnesium and Silicon on the lateral overgrowth of GaN patterned substrates by Metal Organic Vapor Phase Epitaxy


S. Haffouz, B. Beaumont, Pierre GIBART
Centre de Recherche sur l'Hétéroépitaxie et ses Applications, CRHEA-CNRS

This article was received on Thursday, June 4, 1998 and accepted on Thursday, July 16, 1998.

Abstract

Metalorganic vapor phase epitaxy was used to achieve selective regrowth of undoped, Mg- and Si-doped GaN on a silicon nitride patterned mask, capping a GaN epitaxial layer deposited on (0001) sapphire substrate. Hexagonal openings in the mask defined into 10 µm diameter circles separated by 5µm were used as a pattern for the present study. Uniform undoped and Mg-doped GaN hexagonal pyramids, delimited by C (0001) and R {1(-1)01} facets, were achieved with a good selectivity. Si-doped GaN hexagonal pyramids delimited by vertical {1(-1)00} facets and (0001) top facet were obtained for a high SiH4 flow rate in the vapor phase. We found that the GaN growth rates VR and VC, measured in the R <1(-1)01> and C <0001> directions respectively, were drastically affected by the Mg and Si incorporation. By adjusting the Mg partial pressure in the growth chamber, the VR/VC ratio can be increased. Hence, the delimiting top C facet do not vanish as usually observed in undoped GaN selective regrowth but conversely expands. On the other hand, under proper growth conditions, 20µm-high Si-doped GaN columns were obtained.

Outline

  • Introduction
  • Experimental
  • Selective growth of undoped GaN
  • Selective growth of Mg-doped GaN
  • Selective growth of Si-doped GaN
  • Conclusion
  • Acknowledgments
  • Linked Pages

    Cite this article as: MRS Internet J. Nitride Semicond. Res. 3, 8(1998).

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