Properties of InGaN deposited on Glass at Low Temperature


Tilman Beierlein , S. Strite
IBM Research Division, Zurich Research Laboratory

A. Dommann
Neu-Technikum Buchs

David J. Smith
Center for Solid State Science, Arizona State University

This article was received on Friday, April 25, 1997 and accepted on Monday, September 15, 1997.

Abstract

We have investigated the properties of InGaN grown at low temperature on glass substrates by a plasma enhanced MBE process. The goal of this study was to evaluate the potential of InGaN as an oxide-free, transparent conductor material which could be deposited at or slightly above room temperature with minimal interaction or damage to the underlying material. InxGa1-xN films deposited on glass, even without substrate heating, are highly crystalline, but the crystallinity as measured by x-ray degrades at x < 0.5. The microstructure observed by TEM of InGaN films deposited on unheated substrates is highly columnar, with typical column widths of ~10 nm. The optical absorption spectra of InGaN/glass have a distinct absorption edge at the bandgap, but also high background absorption in the bandgap. InxGa1-xN grown on glass (x > 0.5) is conductive due to its high electron concentration. InN electron Hall mobilities > 20 cm2/Vs when grown at 400°C, and ~ 7 cm2/Vs on unheated substrates were obtained. The addition of GaN degraded the electrical properties of the films to a greater extent than it improved the transparency. As a result, the best transparent conductor films were pure InN which, when deposited at 400°C, were half as transparent in the green as an indium tin oxide film having the same sheet resistance.

Outline

  • Introduction
  • Purpose of the Investigation
  • Background
  • Present Study
  • Experiment
  • Substrates
  • Growth Chamber
  • Characterization
  • X-ray Diffraction Measurements
  • Optical Transmission Measurements
  • Hall Measurements
  • SIMS Measurements
  • TEM Measurements
  • Optimization of the Growth Conditions
  • Variation of N2 Flow and Plasma Power
  • Influence of the growth rate on electrical properties
  • Properties of Optimized InxGa1-xN Deposited on Glass Substrates
  • Experimental Matrix
  • X-ray Characterization of InGaN/Glass
  • Optical Absorption Spectra of InGaN/Glass
  • Electrical Properties of InGaN/glass
  • TEM of InGaN/Glass
  • InGaN/Glass as a Transparent, Oxygen Free Conductor
  • Conclusion
  • Acknowledgments
  • Linked Pages

    Cite this article as: MRS Internet J. Nitride Semicond. Res. 2, 29(1997).

    last updated Thursday, October 15, 1998 11:27:33 AM.

    © 1997-1998 The Materials Research Society MRS Internet Journal of Nitride Semiconductor Research
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